Not sure what the vice versa would be tbh, like physically unfit (fat?) and have a pretty face? something like that I guess.
As I see it, these two things go hand-in-hand in the overwhelming majority of cases. I don't know any guy who is considered attractive but is physically unfit or fat or w/e. All popular guys I know are fit AF, like lean and muscular, visible abs and so on.
Exercise does change the way face looks like if u lose fat and build muscle like I've known guys who lost weight and literally revealed feats on their face that weren't visible, obviously jawlines but more importantly, even dimples and such.